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化学系 | Department Of Chemistry
 

程寒松


 程寒松

1.   简介


 

程寒松,教授,1982年毕业于武汉大学化学系,同年考入吉林大学理论化学研究所研究生,师从我国著名量子化学家唐敖庆教授,1985年获硕士学位。随后赴美留学,1991年获普林斯顿大学博士学位。毕业后即在美国Air Products&Chemicals(气体与化学品公司)工作,任高级研究员职位。2004年参与创建美国能源部氢吸附材料研究中心(由九所美国大学、五个国家实验室和一家跨国公司组成)。并于2004-2009年担任该中心高级研究员和管理委员会委员。2004年被聘为中国地质大学(武汉)特聘教授,任中国地质大学(武汉)理论化学与计算材料科学研究所所长。现任中国地质大学(武汉)可持续能源实验室主任,中国科学院生物能源与过程研究所太阳能与储能技术重点实验室学术委员会副主任,中国地质大学学术委员会委员,《硅酸盐学报》杂志编委会编委,湖北省欧美同学会常务理事,湖北省高级专家协会会员,武汉大学、南京大学兼职教授。

常年招收化学、材料方向硕士研究生3名左右,博士研究生2名,欢迎广大考生联系报考。

联系方式:chghs2@gmail.com     027-67883808   15994221924

 

 

2.    主要成就

近年来,程寒松教授在国内外知名学术刊物中公开发表学术论文达140余篇,在国际顶尖学术刊物中发表论文10余篇,并申请美国专利30余项,部分专利已为德国宝马汽车公司、美国联合技术公司、美国西北太平洋国家实验、美国气体与化学品公司等进行商业化开发。由于在储氢材料研发方面的出色工作,程寒松教授获美国能源部 2010年特殊贡献奖。此外,他领导开发的半导体研发工作创造了高达7000万美元/年的商业价值。近10年来应邀在美国化学会、化学化工年会、材料科学年会上作学术报告11场;应邀在哈佛大学、普林斯顿大学、日本京都大学、德国爱尔兰根大学、奥地利维也纳大学、荷兰格罗宁根大学、西班牙科学院等世界知名的大学和研究机构进行学术报80余场,并与这些大学和研究机构的国际一流科学家建立了广泛与密切的科研合作关系。

2009年底回国工作以来,程寒松教授带领中国地质大学可持续能源实验室学术团队取得了诸多的科研成果,在清洁能源与可持续能源技术、新型吸收式温度调节系统储氢材料设计制备、新型直接燃料电池技术,太阳能转化与存储技术、二氧化碳吸收与转化技术、高效催化剂设计等方面取得了众多成果,其中部分成果已进入商业化阶段。20116月,程寒松教授作为执行主席在北京组织了以氢能科学与技术的发展与战略为主题的第400次香山科学会议并做主题报告。同年10月,程寒松教授作为大会主席在武汉成功地组织了以第十二届全国氢能会议暨两岸三地氢能研讨会2011年获程寒松教授武汉市首届黄鹤英才奖。

3.相关背景

可持续能源实验室

中国地质大学(武汉)可持续能源实验室包括计算化学实验室、有机实验室、无机实验室、电化学实验室及分析测试实验室等,总体面积达600m2。各类实验、分析测试仪器等固定资产近千万元。团队成员包括教授3人、副教授4人,海外兼职特聘教授3人,研究生20余人。实验室以计算设计和实验制备紧密结合为特色和优势,得到了国际同行的认可,取得了显著成绩,已申请美国专利5项;在德国应用化学、物理评论、物理化学等国际权威学术刊物上发表SCI收录论文30余篇;获国家自然科学自然基金资助4项,获美国气体与化学品公司国际合作项目资助达260万元,并与美国哈佛大学、日本京都大学、新加坡国立大学等建立了实质性的合作关系。

4.主要研究方向

1)清洁能源与可持续能源:

a) 储氢材料设计制备;

b) 新型直接燃料电池技术;

c) 锂离子电池正极材料、新型电解质材料;

d) 太阳能的转化与存储技术;

e) 二氧化碳的吸收与转化技术。

2)半导体表面功能薄膜的沉积与生长技术:

a) 原子层沉积技术;

b) 半导体表面功能薄膜的设计及生长技术。

3)高效催化体系的设计:

a) 异相催化反应机理;

b) 新型廉价高效催化剂的设计

5.项目列表

1,《多元稠杂环低共熔液态储氢材料及其氢化/脱氢催化剂的理论设计、制备及反应机理研究》,国家自然科学基金重点项目,项目经费280万元,2013.1-2017.12,主持;

2,《Computational Screening of Sillicon Nitride Precursors for Low Temperature Deposition》,国际合作项目,

项目经费300万元, 2005.9-2012.12,主持 (项目编号201-828-P)

3  国家高层次人才项目经费      1000      万,主持


6.代表性论文    

论文

1.      Huang, L.; Han, B.; Han, B.; Derecskei-Kovacs, A.; Xiao, M.; Lei, X.; O’Neill, M. L.; Pearlstein, R. M.; Chandra, H.; Cheng, H., First-Principles Study of a Full Cycle of Atomic Layer Deposition of SiO2 Thin Films with Di(sec-butylamino)silane and Ozone. The Journal of Physical Chemistry C 2013, 117 (38), 19454-19463.

2.      Hu, Z. B.; Zhou, C. G.; Prabhakar, R. R.; Lim, S. X.; Wang, Y. H.; van Kan, J. A.; Cheng, H. S.; Mhaisalkar, S. G.; Sow, C. H., Rapid reversible electromigration of intercalated K ions within individual MoO3 nanobundle. Journal of Applied Physics 2013, 113 (2).

3.      Han, B.; Sun, Y. B.; Fan, M. H.; Cheng, H. S., On the CO2 Capture in Water-Free Monoethanolamine Solution: An ab Initio Molecular Dynamics Study. Journal of Physical Chemistry B 2013, 117 (19), 5971-5977.

4.      Zhang, Q.; Han, B.; Tang, X.; Heier, K.; Li, J. X.; Hoffman, J.; Lin, M.; Britton, S. L.; Derecskei-Kovacs, A.; Cheng, H., On the Mechanisms of Carbon Formation Reaction on Ni(111) Surface. The Journal of Physical Chemistry C 2012, 116 (31), 16522-16531.

5.      Yang, M.; Han, C. Q.; Ni, G.; Wu, J. P.; Cheng, H. S., Temperature controlled three-stage catalytic dehydrogenation and cycle performance of perhydro-9-ethylcarbazole. International Journal of Hydrogen Energy 2012, 37 (17), 12839-12845.

6.      Yang, M.; Han, B.; Cheng, H., First-Principles Study of Hydrogenation of Ethylene on a HxMoO3(010) Surface. The Journal of Physical Chemistry C 2012, 116 (46), 24630-24638.

7.      Hu, Z. B.; Zhou, C. G.; Zheng, M. R.; Lu, J. P.; Varghese, B.; Cheng, H. S.; Sow, C. H., K-Enriched MoO3 Nanobundles: A Layered Structure with High Electric Conductivity. Journal of Physical Chemistry C 2012, 116 (6), 3962-3967.

8.      Han, B.; Zhang, Q. F.; Wu, J. P.; Karwacki, E. J.; Derecskei, A.; Xiao, M. C.; Lei, X. J.; O'Neill, M. L.; Cheng, H. S., On the Mechanisms of SiO2 Thin-Film Growth by the Full Atomic Layer Deposition Process Using Bis(t-butylamino)silane on the Hydroxylated SiO2(001) Surface. Journal of Physical Chemistry C 2012, 116 (1), 947-952.

9.      Du, Z. Y.; Zhou, C. G.; Gao, Y. J.; Ren, Q.; Zhang, K.; Cheng, H. S.; Wang, W.; Wang, J., Expeditious diastereoselective construction of a thiochroman skeleton via a cinchona alkaloid-derived catalyst. Organic & Biomolecular Chemistry 2012, 10 (1), 36-39.

10.    Zhou, C. G.; Yao, S. J.; Zhang, Q. F.; Wu, J. P.; Yang, M.; Forrey, R. C.; Cheng, H. S., Hydrogen sequential dissociative chemisorption on Ni-n(n=2 similar to 9,13) clusters: comparison with Pt and Pd. Journal of Molecular Modeling 2011, 17 (9), 2305-2311.

11.    Zhang, Q.; Han, B.; Heier, K.; Li, J. X.; Hoffman, J.; Lin, M.; Derecskei-Kovacs, A.; Cheng, H., First Principles Study of Steam Carbon Reaction on γ-Fe(111) Surface. The Journal of Physical Chemistry C 2011, 115 (24), 12068-12076.

12.    Legenski, N.; Zhou, C. G.; Zhang, Q. F.; Han, B.; Wu, J. P.; Chen, L. A.; Cheng, H. S.; Forrey, R. C., Force Fields for Metallic Clusters and Nanoparticles. Journal of Computational Chemistry 2011, 32 (8), 1711-1720.

13.    Ichikawa, K.; Wagatsuma, A.; Szarek, P.; Zhou, C. G.; Cheng, H. S.; Tachibana, A., Electronic stress tensor analysis of hydrogenated palladium clusters. Theoretical Chemistry Accounts 2011, 130 (2-3), 531-542.

14.    Han, B.; Zhou, C. G.; Wu, J. P.; Tempel, D. J.; Cheng, H. S., Understanding CO2 Capture Mechanisms in Aqueous Monoethanolamine via First Principles Simulations. Journal of Physical Chemistry Letters 2011, 2 (6), 522-526.

15.    Zhou, C. G.; Zhang, Q. F.; Chen, L.; Han, B.; Ni, G.; Wu, J. P.; Garg, D.; Cheng, H. S., Density Functional Theory Study of Water Dissociative Chemisorption on the Fe3O4(111) Surface. Journal of Physical Chemistry C 2010, 114 (49), 21405-21410.

16.    Han, B.; Wu, J.; Zhou, C.; Chen, B.; Gordon, R.; Lei, X.; Roberts, D. A.; Cheng, H., First-Principles Simulations of Conditions of Enhanced Adhesion Between Copper and TaN(111) Surfaces Using a Variety of Metallic Glue Materials. Angewandte Chemie International Edition 2010, 49 (1), 148-152.

17.    Chen, S.; Li, J. Y.; Zhou, C. G.; Wu, J. P.; Ternpel, D. J.; Henderson, P. B.; Brzozowski, J. R.; Cheng, H. S., Weak Chemical Complexation of PH3 with Ionic Liquids. Journal of Physical Chemistry B 2010, 114 (2), 904-909.

18.    Chen, L.; Zhang, Q.; Zhang, Y.; Li, W. Z.; Han, B.; Zhou, C.; Wu, J.; Forrey, R. C.; Garg, D.; Cheng, H., A first principles study of water dissociation on small copper clusters. Physical Chemistry Chemical Physics 2010, 12 (33), 9845-9851.

19.    Zhou, C. G.; Wu, J. P.; Chen, L.; Wang, Y.; Cheng, H. S.; Forrey, R. C., Force Field for Copper Clusters and Nanoparticles. Journal of Computational Chemistry 2009, 30 (14), 2255-2266.

20.    Yao, S. J.; Zhou, C. G.; Han, B.; Fan, T.; Wu, J. P.; Chen, L.; Cheng, H. S., Chemisorption of small fullerenes C-n (n=28,32,36,40,44,48,60) on the Si(001)-c(2x1) surface. Physical Review B 2009, 79 (15).

21.    Szarek, P.; Urakami, K.; Zhou, C. G.; Cheng, H. S.; Tachibana, A., On reversible bonding of hydrogen molecules on platinum clusters. Journal of Chemical Physics 2009, 130 (8).

22.    Li, J. Y.; Wu, J. P.; Zhou, C. G.; Han, B.; Lei, X. J.; Gordon, R.; Cheng, H. S., On the Relative Stability of Cobalt- and Nickel-Based Amidinate Complexes Against beta-Migration. International Journal of Quantum Chemistry 2009, 109 (4), 756-763.

23.    Li, J. Y.; Wu, J. P.; Zhou, C. G.; Han, B.; Karwacki, E. J.; Xiao, M. C.; Lei, X. J.; Cheng, H. S., On the Dissociative Chemisorption of Tris(dimethylamino)silane on Hydroxylated SiO2(001) Surface. Journal of Physical Chemistry C 2009, 113 (22), 9731-9736.

24.    Chen, L. A.; Zhou, C. G.; Wu, J. P.; Cheng, H. S., Hydrogen adsorption and desorption on the Pt and Pd subnano clusters - a review. Frontiers of Physics in China 2009, 4 (3), 356-366.

25.    Zhou, C. G.; Yao, S. J.; Wu, J. P.; Forrey, R. C.; Chen, L.; Tachibana, A.; Cheng, H. S., Hydrogen dissociative chemisorption and desorption on saturated subnano palladium clusters (Pd(n), n=2-9). Physical Chemistry Chemical Physics 2008, 10 (35), 5445-5451.

26.    Zhou, C. G.; Li, J. Y.; Chen, S.; Wu, J. P.; Heier, K. R.; Cheng, H. S., First-principles study on water and oxygen adsorption on surfaces of indium oxide and indium tin oxide nanoparticles. Journal of Physical Chemistry C 2008, 112 (36), 14015-14020.

27.    Yao, S. J.; Zhou, C. G.; Wu, J. P.; Li, J.; Han, B.; Cheng, H. S., On the electronic structures and spectroscopic properties of polyyne and its derivatives. International Journal of Quantum Chemistry 2008, 108 (9), 1565-1571.

28.    Kumar, T. J. D.; Zhou, C. G.; Cheng, H. S.; Forrey, R. C.; Balakrishnan, N., Effect of Co doping on catalytic activity of small Pt clusters. Journal of Chemical Physics 2008, 128 (12).

29.    Han, B.; Wu, J.; Zhou, C.; Li, J.; Lei, X.; Norman, J. A. T.; Gaffney, T. R.; Gordon, R.; Roberts, D. A.; Cheng, H., Ab Initio Molecular Dynamics Simulation on the Aggregation of a Cu Monolayer on a WN(001) Surface. The Journal of Physical Chemistry C 2008, 112 (26), 9798-9802.

30.    Chen, L.; Chen, B.; Zhou, C.; Wu, J.; Forrey, R. C.; Cheng, H., Influence of CO poisoning on hydrogen chemisorption onto a Pt-6 cluster. Journal of Physical Chemistry C 2008, 112 (36), 13937-13942.

13/16 cited  7/187 in physics  51/6188  4.814/5.152

 

 

(a) Cheng, H.; Chen, L.; Cooper, A. C.; Sha, X.; Pez, G. P., Hydrogen spillover in the context of hydrogen storage using solid-state materials. Energy & Environmental Science 2008, 1 (3), 338-354. 31/36 cited  41/60 in environment/ecology   871/6188  11.653/12.462;

(b) Cheng, H.; Sha, X.; Chen, L.; Cooper, A. C.; Foo, M.-L.; Lau, G. C.; Bailey Iii, W. H.; Pez, G. P., An Enhanced Hydrogen Adsorption Enthalpy for Fluoride Intercalated Graphite Compounds. Journal of the American Chemical Society 2009, 131 (49), 17732-17733. 16/16 cited  1/302 in chemistry   3/6188  10.677/10.237;

(c) Tempel, D. J.; Henderson, P. B.; Brzozowski, J. R.; Pearlstein, R. M.; Cheng, H., High Gas Storage Capacities for Ionic Liquids through Chemical Complexation. Journal of the American Chemical Society 2008, 130 (2), 400-401. 22/25   1/302 in chemistry   3/6188  10.677/10.237

专利

1)         Cheng H, Lei X, Spence D, Norman J, Robert D, Han B, Zhou C, Wu J. "Method for Suppressing Agglomeration and Improving Semiconductor Device Adhesiveness". Japanese Patent JP2010062555. Application Number: JP2009000188053.

2)         Cheng H, Xiao M, Lal G, Gaffney T, Zhou C, Wu J."Precursor for Accumulating Silicon-Containing Film and Method For Producing and Using the Same". Japanese Patent JP2010043081. Application Number: JP2009000184479.

3)         Cheng H, Lei X, Spence D, Norman J, Robert D, Han B, Zhou C, Wu J. "Materials for adhesion enhancement of copper film on diffusion barriers". European Patent Application EP2154717. Application Number: EP20090167949.

4)         Cheng H, Xiao M, Lal G, Zhou C, Wu J. "Precursors for Depositing Silicon-containing Films and Methods for Making and Using Same". European Patent Application EP2154141.A3. Application Number: EP20090167403.

5)         Cheng H, Lei X, Spence D, Norman J, Robert D, Han B, Zhou C, Wu J. "Materials for Adhesion Enhancement of Copper Film on Diffusion Barriers". US patent US7919409. Application Number: 12/192603.

6)         Cheng H, Lei X, Spence D, Norman J, Robert D, Han B, Zhou C, Wu J. "Materials for Adhesion Enhancement of Copper Film on Diffusion Barriers". US patent application US20100038785. Application Number: 12/192603.

7)         Cheng H, Xiao M, Lal G, Zhou C, Wu J. "Precursors for Depositing Silicon-containing Films and Methods for Making and Using Same". US patent application US20100041243. Application Number: 12/190125.

专著

1)         Zhou, C.; Cheng, H., Chapter 7 Density functional theory study of water dissociative chemisorption on metal oxide surfaces In Chemical Sensors: Simulation and Modeling Volume 1: Microstructural Characterization and Modeling of Metal Oxides  Ghenadii, K., Ed. Momentum Press: New York, 2012; Vol. 1, pp 263-292.

2)         Chen, L.; Yang, M.; Cheng, H., Chapter 8 First-principles studies of hydrogen spillover mechanisms on metal oxides. In Chemical Sensors: Simulation and Modeling Volume 1: Microstructural Characterization and Modeling of Metal Oxides, Ghenadii, K., Ed. Momentum Press  New York, 2012; Vol. 1, pp 293-316.